Enantioselective Cyano-Alkoxycarbonylation of α-Oxoesters Promoted by Br?nsted Acid-Lewis Base Cooperative Catalysts

DOI: 10.1021/acs.orglett.5b03093

Source and publish data:

Organic Letters p. 6070 - 6073 (2015)

Update date:2022-08-06

Topics:

Authors:

Ishihara, Kazuaki

Ogura, Yoshihiro

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Article abstract of DOI:10.1021/acs.orglett.5b03093

The highly enantioselective cyano-alkoxycarbonylation of α-oxoesters with alkyl cyanoformates is promoted by a new chiral Br?nsted acid-Lewis base cooperative organocatalyst. The present catalysis can be performed at room temperature under nitrogen or air.

Full text of DOI:10.1021/acs.orglett.5b03093

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