Journal of Organic Chemistry p. 4195 - 4205 (1992)
Update date:2022-09-26
Topics: Reaction Conditions Steric Effects Electronic effects
Snider, Barry B.
Zhang, Qingwei
Dombroski, Mark A.
Chlorine substituents on the alkene control the regioselectivity of the cyclization of 5-hexenyl or 6-heptenyl radicals generated by oxidation of an acetoacetate ester or 1,3-diketone with Mn(OAc)3*2H2O. 6-Exo-cyclization of the radicals obtained by oxida
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