Tetrahedron Letters p. 2099 - 2102 (1992)
Update date:2022-07-29
Topics:
Burk, Mark J.
Feaster, John E.
A procedure for the catalytic asymmetric intramolecular hydrosilylation of α- and β-hydroxyketones has been developed. A cationic rhodium (I) catalyst bearing the new chiral diphosphine (R,R)-i-Pr-DuPHOS affords the product diols in up to 93% ee.
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