Tetrahedron Letters p. 2099 - 2102 (1992)
Update date:2022-07-29
Topics:
Burk, Mark J.
Feaster, John E.
A procedure for the catalytic asymmetric intramolecular hydrosilylation of α- and β-hydroxyketones has been developed. A cationic rhodium (I) catalyst bearing the new chiral diphosphine (R,R)-i-Pr-DuPHOS affords the product diols in up to 93% ee.
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Doi:10.1248/cpb.40.1094
(1992)Doi:10.1016/S0022-328X(00)93976-7
(1982)Doi:10.1002/ardp.19683010511
(1968)Doi:10.1021/om030468l
(2004)Doi:10.1081/NCN-120025236
(2003)Doi:10.1021/jo01059a048
(1962)
