A Concise Synthesis of Fredericamycin A DEF Ring System: Cycloaddition reactions of 1-Aza-1,3-butadienes

DOI: 10.1021/jo00040a044

Source and publish data:

Journal of Organic Chemistry p. 3974 - 3977 (1992)

Update date:2022-08-03

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Authors:

Boger, Dale L.

Zhang, Minsheng

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Article abstract of DOI:10.1021/jo00040a044

A concise four-step synthesis of fredericamycin A DEF ring system is detailed based on the LUMO_diene-controlled Diels-Alder reaction of N-sulfonyl-1-azadiene 3 for introduction of the pyridone F ring.

Full text of DOI:10.1021/jo00040a044

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