Total Synthesis of (+/-)-Cyclolaurene, (+/-)-Epicyclolaurene and (+/-)-β-Cuparenone

DOI: 10.1016/0040-4020(92)85016-8

Source and publish data:

Tetrahedron p. 3429 - 3436 (1992)

Update date:2022-07-29

Topics:

Authors:

Srikrishna, Adusumilli

Krishnan, Kathiresan

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Article abstract of DOI:10.1016/0040-4020(92)85016-8

The first total synthesis of (+/-)-cyclolaurene (1) and (+/-)-epicyclolaurene (5), and a new route to (+/-)-β-cuparenone (4) are reported.Thus, orthoester Claisen rearrangement of the cinnamyl alcohol 8 furnished the ene-ester 10.Anhydrous CuSO4 catalysed

Full text of DOI:10.1016/0040-4020(92)85016-8

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