Total Synthesis of (+/-)-Cyclolaurene, (+/-)-Epicyclolaurene and (+/-)-β-Cuparenone

DOI: 10.1016/0040-4020(92)85016-8

Source and publish data:

Tetrahedron p. 3429 - 3436 (1992)

Update date:2022-07-29

Topics:

Authors:

Srikrishna, Adusumilli

Krishnan, Kathiresan

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(92)85016-8

The first total synthesis of (+/-)-cyclolaurene (1) and (+/-)-epicyclolaurene (5), and a new route to (+/-)-β-cuparenone (4) are reported.Thus, orthoester Claisen rearrangement of the cinnamyl alcohol 8 furnished the ene-ester 10.Anhydrous CuSO4 catalysed

Full text of DOI:10.1016/0040-4020(92)85016-8

Products guided by the article

Product name:Ethyl 3,4-dimethyl-3-(4-methylphenyl)-pent-4-enoate

Cas No:141972-49-8

R&D Labs maybe for 141972-49-8

UNION PHARMPRO CO.,LTD

Contact:18710867521(wechat)

Address:Rm10516,Galaxy Tech Building #2,No.25 Tangyan Rd,Hi-Tech Zone,Xi'an, China
Cangzhou Senary Chemical Science-tech Co., Ltd

Contact:+86-317-3563899, 3563699

Address:168 Jinde Road, Cangzhou, Hebei, China
Yancheng Smiling Imp & Exp Co., Ltd.

Contact:+86-515-83173586

Address:Rm1207, BLD#03, Phoenix Plaza, Juheng Road, Yancheng, Jiangsu, P.R. China
Hangzhou Share Chemical Co., Ltd(expird)

Contact:+86-57187093700

Address:Hang Xing Road
Nantong Baokai Chemical Co., Ltd (Hangzhou Baokai Bio-Chemicals Co.,Ltd.)

Contact:+86-513-83886111

Address:No. 68 Suzhou road ,Binjiang Fine Chemical Industrial Park , Beixin town, Qidong city ,Jiangsu province

Relevant to this article

N-Functionalised TsDPEN catalysts for asymmetric transfer hydrogenation; Synthesis and applications

Doi:10.1016/j.tetlet.2015.09.135
(2015)
Asymmetric catalytic conjugate addition of acetaldehyde to nitrodienynes/nitroenynes: Applications to the syntheses of (+)-α-lycorane and chiral β-alkynyl acids

Doi:10.1021/ol501158b
(2014)
Pyrene-based fluorescent ambidextrous gelators: Scaffolds for mechanically robust swnt-gel nanocomposites

Doi:10.1002/chem.201303401
(2014)
Novel and efficient synthesis of 4-indazolyl-1,3,4-trisubstituted pyrazole derivatives

Doi:10.1080/00397911.2013.862724
(2014)
Antimicrobial activity of the marine alkaloids, clathrodin and oroidin, and their synthetic analogues

Doi:10.3390/md12020940
(2014)
Unexpected neutral aza-macrocycle complexes of sodium

Doi:10.1039/c4cc01407c
(2014)

Article Doi