
Tetrahedron p. 3429 - 3436 (1992)
Update date:2022-07-29
Topics:
Srikrishna, Adusumilli
Krishnan, Kathiresan
The first total synthesis of (+/-)-cyclolaurene (1) and (+/-)-epicyclolaurene (5), and a new route to (+/-)-β-cuparenone (4) are reported.Thus, orthoester Claisen rearrangement of the cinnamyl alcohol 8 furnished the ene-ester 10.Anhydrous CuSO4 catalysed
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