Asymmetric synthesis of a β-lactam framework via the conjugate addition of amidocuprates(I) to chiral enoates

DOI: 10.1246/bcsj.68.2103

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2103 - 2111 (1995)

Update date:2022-09-26

Topics: Workup and Purification Reaction Conditions Stereochemical Control Reaction Mechanism

Authors:

Asao Asao

Uyehara Uyehara

Tsukada Tsukada

Yamamoto

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Article abstract of DOI:10.1246/bcsj.68.2103

Amidocuprate(I) reagents {Li[Cu(NR₂)₂]} and higher order cyanocuprates(I) {Li₂[Cu(CN)(NR₂)₂]} have been developed as a new class of nitrogen nucleophiles. These reagents underwent regioselective 1,4-a

Full text of DOI:10.1246/bcsj.68.2103

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