Towards the synthesis of calyculin: A synthetic intermediate corresponding to the C(26)-C(37) fragment

DOI: 10.1016/0040-4039(92)88107-G

Source and publish data:

Tetrahedron Letters p. 1937 - 1940 (1992)

Update date:2022-08-04

Topics: Synthesis Intermediates

Authors:

Vaccaro Vaccaro

Levy Levy

Sawabe Sawabe

Jaetsch Jaetsch

Masamune

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Article abstract of DOI:10.1016/0040-4039(92)88107-G

The synthetic intermediate 2 corresponding to the C(26)-C(37) fragment of calyculin A (1) has been synthesized. Key transformations include the efficient one-pot construction of the oxazole system embedded in 1 without epimerization α [C(30)] to the ring,

Full text of DOI:10.1016/0040-4039(92)88107-G

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