Towards the synthesis of calyculin: A synthetic intermediate corresponding to the C(26)-C(37) fragment

DOI: 10.1016/0040-4039(92)88107-G

Source and publish data:

Tetrahedron Letters p. 1937 - 1940 (1992)

Update date:2022-08-04

Topics: Synthesis Intermediates

Authors:

Vaccaro Vaccaro

Levy Levy

Sawabe Sawabe

Jaetsch Jaetsch

Masamune

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(92)88107-G

The synthetic intermediate 2 corresponding to the C(26)-C(37) fragment of calyculin A (1) has been synthesized. Key transformations include the efficient one-pot construction of the oxazole system embedded in 1 without epimerization α [C(30)] to the ring,

Full text of DOI:10.1016/0040-4039(92)88107-G

Products guided by the article

Product name:tert-Butyl-((3E,5E)-(S)-6-iodo-2,4,5-trimethyl-hexa-3,5-dienyloxy)-diphenyl-silane

Cas No:142387-20-0

R&D Labs maybe for 142387-20-0

ZHEJIANG NHU COMPANY LTD.

Contact:86-575-86132822，86-575-86085355

Address:No.418 Dadao West Road,Qixing Street,Xinchang, Zhejiang Province, China.
Quzhou Ruiyuan chemical Co., Ltd

Contact:+86-570-3039321/3039361/3039308

Address:18# Huayang Road,Quzhou High-tech Industrial Park, Zhejiang China.
shanghai jinshan pharmaceutical Co.,Ltd

Contact:021-57363011，13681638167

Address:No. 7966 Tingfeng Road,Jinshan,Shanghai,China
puyang hongda shengdao new material co.,ltd.

Contact:+86-393- 4896278

Address:No.29 East Zhongyuan Road
taizhou creating bio-pharm co.,ltd.

Contact:+86- 576- 88827176

Address:715 room ,unit A.junyue Building,Jiaojiang,Taizhou,Zhejiang,China

Relevant to this article

A Highly Selective Methodology for the Direct Conversion of Acetals to Esters

Doi:10.1021/jo00044a042
(1992)
A Novel Class of Cyclic β-Dicarbonyl Leaving Groups and Their Use in the Design of Benzisothiazolone Human Leukocyte Elastase Inhibitors

Doi:10.1021/jm00023a008
(1995)
Synthesis of enantiomerically enriched triarylmethanes by enantiospecific suzuki-miyaura cross-coupling reactions

Doi:10.1021/ja412159g
(2014)
Heterocyclic amides: Inhibitors of acyl-CoA:cholesterol O-acyl transferase with hypocholesterolemic activity in several species and antiatherosclerotic activity in the rabbit

Doi:10.1021/jm9604033
(1996)
2. Tetraethynylethenes: Fully Cross-Conjugated ?-Electron Chromophores and Molecular Scaffolds for All-Carbon Networks and Carbon-Rich Nanomaterials

Doi:10.1002/hlca.19950780104
(1995)
Chemical Synthesis of 13C-labelled Monomers for the Solid-Phase and Template Controlled Enzymatic Synthesis of DNA and RNA Oligomers

Doi:10.1016/S0040-4039(00)73458-7
(1994)

Article Doi