Towards the synthesis of calyculin: A synthetic intermediate corresponding to the C(26)-C(37) fragment

DOI: 10.1016/0040-4039(92)88107-G

Source and publish data:

Tetrahedron Letters p. 1937 - 1940 (1992)

Update date:2022-08-04

Topics: Synthesis Intermediates

Authors:

Vaccaro Vaccaro

Levy Levy

Sawabe Sawabe

Jaetsch Jaetsch

Masamune

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(92)88107-G

The synthetic intermediate 2 corresponding to the C(26)-C(37) fragment of calyculin A (1) has been synthesized. Key transformations include the efficient one-pot construction of the oxazole system embedded in 1 without epimerization α [C(30)] to the ring,

Full text of DOI:10.1016/0040-4039(92)88107-G

Products guided by the article

Product name:tert-Butyl-((3E,5E)-(S)-6-iodo-2,4,5-trimethyl-hexa-3,5-dienyloxy)-diphenyl-silane

Cas No:142387-20-0

R&D Labs maybe for 142387-20-0

Hubei Vanz Pharm Co.,Ltd

website:http://www.vanzpharm.com/en/index.html

Contact:86-27-84492310

Address:FANHU INDUSTRY PARK
NEWSTAR CHEM ENTERPRISE LTD.

Contact:0572-2722882

Address:1201,F3,xinghuibandao,
SAGECHEM LIMITED

website:http://www.sagechem.com

Contact:+86-571-86818502

Address:Room C1301, New Youth Plaza, 8 Jia Shan Road, Hangzhou, China
Taizhou Crene Biotechnology co.ltd

Contact:86-576-88813233 88205808

Address:Economic Developed Zone of Taizhou Zhejiang China
Chengdu Biopurify Phytochemicals Ltd.

website:http://www.phytopurify.com

Contact:+86-28-82633397

Address:2F,No.11 Building,No.388 Rongtaidadao CNSTP,Wenjiang Zone,Chengdu,Sichuan, China

Relevant to this article

A Highly Selective Methodology for the Direct Conversion of Acetals to Esters

Doi:10.1021/jo00044a042
(1992)
A Novel Class of Cyclic β-Dicarbonyl Leaving Groups and Their Use in the Design of Benzisothiazolone Human Leukocyte Elastase Inhibitors

Doi:10.1021/jm00023a008
(1995)
Synthesis of enantiomerically enriched triarylmethanes by enantiospecific suzuki-miyaura cross-coupling reactions

Doi:10.1021/ja412159g
(2014)
Heterocyclic amides: Inhibitors of acyl-CoA:cholesterol O-acyl transferase with hypocholesterolemic activity in several species and antiatherosclerotic activity in the rabbit

Doi:10.1021/jm9604033
(1996)
2. Tetraethynylethenes: Fully Cross-Conjugated ?-Electron Chromophores and Molecular Scaffolds for All-Carbon Networks and Carbon-Rich Nanomaterials

Doi:10.1002/hlca.19950780104
(1995)
Chemical Synthesis of 13C-labelled Monomers for the Solid-Phase and Template Controlled Enzymatic Synthesis of DNA and RNA Oligomers

Doi:10.1016/S0040-4039(00)73458-7
(1994)

Article Doi