N-Substituted Pyrrolidin-3-ones as Heterocyclic Building Blocks. Enantioselective Synthesis of 8-Epi- and 1,8,8a-Triepi-castanospermine

DOI: 10.1039/c39920000166

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 166 - 168 (1992)

Update date:2022-08-03

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Authors:

Gallagher, Timothy

Giles, Melvyn

Subramanian, R. Sankara

Hadley, Michael S.

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Article abstract of DOI:10.1039/c39920000166

Regioselective aldol reaction of dianion 1 with aldehyde 5 provides the basis of a new approach to the construction of polyhydroxy indolizidines and the application of this methodology to the synthesis of 8-epicastanospermine 11 and 1,8,8a-triepicastanosp

Full text of DOI:10.1039/c39920000166

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