N-Substituted Pyrrolidin-3-ones as Heterocyclic Building Blocks. Enantioselective Synthesis of 8-Epi- and 1,8,8a-Triepi-castanospermine

DOI: 10.1039/c39920000166

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 166 - 168 (1992)

Update date:2022-08-03

Topics:

Authors:

Gallagher, Timothy

Giles, Melvyn

Subramanian, R. Sankara

Hadley, Michael S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920000166

Regioselective aldol reaction of dianion 1 with aldehyde 5 provides the basis of a new approach to the construction of polyhydroxy indolizidines and the application of this methodology to the synthesis of 8-epicastanospermine 11 and 1,8,8a-triepicastanosp

Full text of DOI:10.1039/c39920000166

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2-[(R)-((4S,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hydroxy-methyl]-3-oxo-pyrrolidine-1-carboxylic acid ethyl ester

Cas No:142394-37-4

R&D Labs maybe for 142394-37-4

Shanghai Gsyn Chemical Co.,Ltd.

Contact:86-021-67158290

Address:86-021-67158291
Zhejiang Kangfeng Chemical Co.,LTD.

Contact:+86-579-86709687

Address:Xueshizhai Industrial Zone, Weishan Town,Dongyang City, Zhejiang Province ,China
Yangzhou Siyu Chemical Co.,Ltd.

Contact:+86-514-87325867 13358126196

Address:Room 620 Exposition Pavilion，No. 98 Huaihai Road,Guangling District，Yangzhou City, Jiangsu Province
Improve Medical Technology(Nanxiong) Co., Ltd

Contact:86-751-3836997

Address:No.33, Pingan First Road, Fine Chemical Industry Base, Nanxiong City, Shaoguan, Guangdong, China
Shanghai Rainbow Chemistry Co., Ltd.

Contact:+86-21-64968086-5815/5812

Address:3rd floor, Building 7, 251 Faladi Road, Zhangjiang Hi-Tech Park, Pudong District, Shanghai, P.R. China

Relevant to this article

Polyfunctional pyrazoles. 7. Ethyl 1-aryl-4-formylpyrazole-3-carboxylates in the synthesis of 2-aryl-2,4-dihydro-6H-thieno-[3,4-c]pyrazol-6-ones

Doi:10.1007/s10593-013-1171-y
(2013)
Preparation of New Nitrogen-Bridged Heterocycles. 29. Reinvestigation on the Dehydrogenation Reaction of 5,5a-Dihydropyrido<2,1-c>thieno<3,2-e><1,4>thiazine Derivatives

Doi:10.1246/bcsj.65.1244
(1992)
Modular pyridine synthesis from oximes and enals through synergistic copper/iminium catalysis

Doi:10.1021/ja312346s
(2013)
Hydrophilic pyrazine-based phosphane ligands: Synthesis and application in asymmetric hydride transfer and H₂-hydrogenation of acetophenone

Doi:10.1016/j.tetlet.2013.01.108
(2013)
Chiral Recognition Studies of α-(Nonafluoro- tert -butoxy)carboxylic Acids by NMR Spectroscopy

Doi:10.1021/acs.joc.5b00706
(2015)
Asymmetric synthesis of cis-2,5-disubstituted pyrrolidine, the core scaffold of β₃-AR agonists

Doi:10.1021/ol400252p
(2013)

Article Doi