Diastereoselective Diels-Alder reactions with chiral sulfinyl derivatives as dienophiles under high pressure

DOI: 10.1016/S0957-4166(00)82293-4

Source and publish data:

Tetrahedron Asymmetry p. 609 - 612 (1992)

Update date:2022-08-02

Topics:

Authors:

Fuji Fuji

Tanaka Tanaka

Abe Abe

Matsumoto

Taga Taga

Miwa Miwa

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Article abstract of DOI:10.1016/S0957-4166(00)82293-4

Using the high pressure technique, asymmetric Diels-Alder reaction utilizing chiral 2-nitro-1-sulfinylolefins and dienes proceeded smoothly to give highly functionalized cyclohexene derivatives with satisfactory chemical yield and high diastereomeric exce

Full text of DOI:10.1016/S0957-4166(00)82293-4

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Product name:(3aR,4R,7S,7aS)-3a-Nitro-7a-((S)-(S)-2-phenyl-propane-1-sulfinyl)-2,3,3a,4,7,7a-hexahydro-1H-4,7-methano-indene

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