Stereoselective synthesis of 4′-C-branched 2,′3′-didehydro-2′-dideoxy nucleosides based on SnCl4-promoted allylic rearrangement

DOI: 10.1016/S0040-4039(00)78874-5

Source and publish data:

Tetrahedron Letters p. 2841 - 2844 (1992)

Update date:2022-09-26

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Authors:

Haraguchi, Kazuhiro

Tanaka, Hiromichi

Itoh, Yoshiharu

Saito, Shigeru

Miyasaka, Tadashi

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Article abstract of DOI:10.1016/S0040-4039(00)78874-5

Based on SnCl₄-[promoted allylic rearrangement between a 3′,4′-unsaturated uracil nucleoside and organosilicon reagents, stereoselective introduction of carbon functionalities to the 4′-position has been accomplished, disclosing a new entry for

Full text of DOI:10.1016/S0040-4039(00)78874-5

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