Stereoselectivity in the Coupling Reaction between 2-Phenylthio-2,3-dideoxyribose and Silylated Pyrimidine Bases

DOI: 10.1246/cl.1990.1459

Source and publish data:

Chemistry Letters p. 1459 - 1462 (1990)

Update date:2022-08-03

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Authors:

Kawakami, Hiroshi

Ebata, Takashi

Koseki, Koshi

Matsushita, Hajime

Naoi, Yoshitake

Itoh, Kazuo

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Article abstract of DOI:10.1246/cl.1990.1459

Coupling reaction between 2-α-phenylthio-2,3-dideoxyribose and silylated pyrimidine bases in the presence of SnCl4 proceeded stereoselectively to give the β-anomers.These nucleosides were converted to 2',3'-dideoxy-2',3'-didehydronucleosides by oxidation

Full text of DOI:10.1246/cl.1990.1459

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