Journal of the American Chemical Society p. 6850 - 6857 (1992)
Update date:2022-07-30
Topics:
Pickard, Simeon T.
Smith, Howard E.
Polavarapu, Prasad L.
Black, Thomas M.
Rauk, Arvi
Yang, Danya
Both enantiomers of trans-2,3-dimethyloxirane-d0, trans-2,3-dimethyloxirane-d2, and trans-2,3-dimethyloxirane-2,3-d2 are synthesized. Vibrational circular dichroism (VCD) spectra for these compounds are obtained in the 1600-700-cm-1 region. Ab initio theoretical calculations using the localized molecular orbital method (LMO-VCD) and the vibronic coupling theoretical method (VCT) are also obtained for these molecules. A comparison of the theoretical VCD predictions with the corresponding experimental observations demonstrates that the observed VCD features are satisfactorily reproduced by the theories, indicating that absolute configurations can be confidently determined using vibrational circular dichroism.
View MoreBeijing Green Guardee Technology CO,.LTD
Contact:+86-10-69706062
Address:F2 BLdj,5 No.37 Chaoqian Road
Tianjin Te-An Chemtech Co., Ltd.(expird)
Contact:+86-22-65378638
Address:A5-8, No.80 Haiyun Street, TEDA
Tianjin Ingenochem Technology Co.,Ltd
Contact:+86-22-23677060
Address:Hitech Green Industry Park K2-9-602, Nankai district
Hangzhou Dingyan Chem Co., Ltd
website:http://www.dingyanchem.com
Contact:86-571-87157530-8007
Address:RM.1118,NO.1 Building, Baiyun Tower,Jianggan Area, Hangzhou city, China,310004
Shandong Yaroma Perfumery Co., Ltd.
Contact:+86- 531- 88024598
Address:7-702 Caizhi Central, 59 Gong Ye South Road, Jinan City,250101, P. R. China
Doi:10.1016/j.tet.2013.01.064
(2013)Doi:10.1021/om200602k
(2011)Doi:10.1021/om400046r
(2013)Doi:10.1021/acs.orglett.8b00196
(2018)Doi:10.1021/ja311430r
(2013)Doi:10.1055/s-0032-1318300
(2013)