Journal of the Chemical Society. Chemical communications p. 786 - 788 (1992)
Update date:2022-08-04
Topics:
Hamley, Peter
Helmchen, Guenter
Holmes, Andrew B.
Marshall, David R.
MacKinnon, John W. M.
et al.
The diethylaluminium chloride-catalysed cycloaddition of cyclopentadiene to the (S)-lactate-derived N-toluene-p-sulfonyliminoacetate 5 gives mainly (76percent diastereoisomeric excess, d.e.) the adduct 9 (X-ray structure); the (R)-pantolactone-derived iminoacetate 6 similarly gives (70percent d.e.) the adduct 8 which is correlated via the methyl esters 11 compound 9.
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