An Intramolecular Diels-Alder Approach to the Cis Ring Fused Isomer of the 25-Hydroxy Vitamin D2 Grundmann Ketone

DOI: 10.1021/jo00042a014

Source and publish data:

Journal of Organic Chemistry p. 4380 - 4385 (1992)

Update date:2022-08-04

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Authors:

Wilson, Stephen R.

Jacob, Linda

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Article abstract of DOI:10.1021/jo00042a014

Stereospecific Claisen and intramolecular Diels-Alder reactions of chiral ester synthon 4 results in conversion of a single asymmetric center of commercially available ester 4 to a vitamin D synthon, the C/D cis Grundmann ketone 3.The addition of propenyl

Full text of DOI:10.1021/jo00042a014

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