Oxo-, Nitrido- and Imino-osmium(VI) Complexes with a Sterically Bulky Chelating Alkoxide Ligand

DOI: 10.1039/DT9920001657

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1657 - 1662 (1992)

Update date:2022-08-03

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Authors:

Li, Zao-Ying

Yu, Wing-Yiu

Che, Chi-Ming

Poon, Chung-Kwong

Wang, Ru-Ji

Mak, Thomas C. W.

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Article abstract of DOI:10.1039/DT9920001657

The synthesis and Characterization of Dioxoosmium(VI) complexes cis- and trans- (L'= NH2Bu^t, pyridine or 4-tert-butylpyridine), the nitrido complex , and imido complexes and are described.The crystal structures of and t)>*0.5 C6H14 have been determined: the Os<*>N and average Os=O bond distances are 1.634(5) and 1.741(5) Angstroem, respectively.

Full text of DOI:10.1039/DT9920001657

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