Organometallics p. 2748 - 2750 (1992)
Update date:2022-07-30
Topics:
Anselme
Ranaivonjatovo
Escudié
Couret
Satgé
Bis(2,4,6-triisopropylphenyl)(fluorenylidene)-stannene-diethyl ether (1a), a new stable compound with a formal tin-carbon double bond, has been synthesized by dehydrofluorination of the corresponding fluoro-stannane with tert-butyllithium; it has been characterized by NMR (δ(119Sn) + 288 ppm, δ(13C) +133.85 ppm) and UV spectroscopy (λmax 542 nm) and by electrophilic addition reactions to the tin-carbon unsaturation.
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Doi:10.1016/j.ejmech.2021.113244
(2021)Doi:10.1007/BF00473973
(1990)Doi:10.1007/BF00473984
(1990)Doi:10.1002/anie.201607579
(2016)Doi:10.1021/ja101583m
(2010)Doi:10.1021/jm00111a030
(1991)
