Journal of Organic Chemistry p. 4786 - 4787 (1992)
Update date:2022-07-30
Topics:
Tour, James M.
Pendalwar, Shekhar L.
Kafka, Cynthia M.
Cooper, Joel P.
Treatment of hydrated RhCl3 and Cu(NO3)2 in THF and H2O with triethoxysilane affords a highly chemo- and stereoselective catalyst system for the reduction of alkynes to Z-alkenes while alkyl-NO2, aryl-NO2, N-carbobenzyloxy, hydroxy, ester, enoate, benzyloxy, alkyl bromide, aryl bromide, and enone moieties remain unaffected.
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Doi:10.1055/s-1992-26153
(1992)Doi:10.1002/anie.201812646
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