Quantitative Treatment of Rate Enhancement Due to F-strain in the Solvolysis of (Z)-2-Ethylidene-1-adamantyl Mesylate and Halides

DOI: 10.1016/S0040-4039(00)92082-3

Source and publish data:

Tetrahedron Letters p. 3335 - 3338 (1992)

Update date:2022-08-06

Topics:

Authors:

Takeuchi, Ken'ichi

Ohga, Yasushi

Munakata, Motohiro

Kitagawa, Toshikazu

Kinoshita, Tomomi

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Article abstract of DOI:10.1016/S0040-4039(00)92082-3

The Z:E rate ratios for the trifluoroethanolysis at 25 deg C of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively, whose logarithms are linearly correlated with MM2 steric energies and Hansch's Es values.

Full text of DOI:10.1016/S0040-4039(00)92082-3

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