Ring Closure of 2,2-Dimethyloct-7-en-3-yl Radical: A System Exhibiting Unusual Solvent Dependence

DOI: 10.1016/S0040-4020(01)81238-2

Source and publish data:

Tetrahedron p. 4641 - 4648 (1992)

Update date:2022-08-02

Topics:

Authors:

Beckwith, Athelstan L. J.

Cliff, Matthew D.

Schiesser, Carl H.

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Article abstract of DOI:10.1016/S0040-4020(01)81238-2

The ring closure of the 2,2-dimethyloct-7-en-3-yl radical (1) has been studied.In hexane at 25 deg C, reaction of the radical precursor, O-(2,2-dimethyloct-7-en-3-yl)-O-phenylthionocarbonate (8) with tri-n-butyltin hydride (AIBN initiator) proceeds to giv

Full text of DOI:10.1016/S0040-4020(01)81238-2

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