Chemistry Letters p. 1101 - 1104 (1992)
Update date:2022-08-02
Topics:
Miyashita, Masaaki
Hoshino, Masahide
Yoshikoshi, Akira
Kawamine, Katsumi
Yoshihara, Kousei
Irie, Hiroshi
The Prelog-Djerassi lactone, a key intermediate for the synthesis of several medicinally important macrolide antibiotics, and protomycinolide IV, a 16-membered macrolide, have been synthesized by employing the recently developed stereospecific methylation of γ,δ-epoxy acrylates by trimethylaluminum as key steps.
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