Journal of the Chemical Society. Chemical communications p. 908 - 910 (1992)
Update date:2022-08-04
Topics:
Seto, Hideharu
Kosemura, Hajime
Fujimoto, Yasuo
Upon irradiation 2-acyloxy-1-methoxycarbonylcyclohexenes readily undergo photo-Fries rearrangement to give 2-acyl-2-methoxycarbonylcyclohexanones in good yields and among them 2-aroyloxy-1-methoxycarbonylcyclohexenes also undergo a novel 1,5-aroyl migration according to irradiation conditions to give 4-aroyl-2-methoxycarbonylcyclohexanones, which result from 1,3-aroyl migration following photo-Fries rearrangement.
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