Tetrahedron p. 4439 - 4458 (1992)
Update date:2022-08-04
Topics:
Gennari, Cesare
Vieth, Siegfried
Comotti, Angiolina
Vulpetti, Anna
Goodman, Jonathan M.
Paterson, Ian
Transition state modelling of the aldol reaction of Z enol borinates with chiral α-methyl aldehydes (see Schemes 4 and 6) suggests that three transition structures (F, AF, R) play a dominant role in controlling π-facial selectivity. The "Felkin" structure
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