Stereoselective Synthesis of Highly Substituted γ-Lactones by Diastereoselective Alkylation of (α-Benzenesulfonyl) Derivatives with Unusual Facial Selectivity

DOI: 10.1021/jo00105a027

Source and publish data:

Journal of Organic Chemistry p. 8081 - 8091 (1994)

Update date:2022-09-26

Topics: Stereoselective synthesis Diastereoselective alkylation Facial selectivity

Authors:

Rodriguez, Carmen M.

Martin, Tomas

Ramirez, Miguel A.

Martin, Victor S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00105a027

The oxidation of α-(phenylthio) γ-lactones obtained by the base-induced cyclization of enantiomerically enriched γ-<(phenylthio)acyl>-α,β-unsaturated esters to sulfones in those cases where the α-carbon has an available proton and further basic alkylation

Full text of DOI:10.1021/jo00105a027

Products guided by the article

Product name:Methyl (2R,3R,4S)-<4-(benzenesulfonyl)-4-butyl-5-oxo-2-propyltetrahydrofuran-3-yl>acetate

Cas No:142968-34-1

R&D Labs maybe for 142968-34-1

Chengdu Boon Stream Chemical Industry Co.,Ltd.

Contact:+86-28-83156758

Address:No.859,Dongzikou Road,Jinniu District,Chengdu,Sichuan,P.R.China
Jiangsu King Road New Materials Co., Ltd.

website:http://www.jskingroad.com

Contact:0519-85720726 0519-85720721 15006126856

Address:No.1,Weihua Road,Xinbei District,Changzhou City,Jiangsu Province
puyang hongda shengdao new material co.,ltd.

Contact:+86-393- 4896278

Address:No.29 East Zhongyuan Road
Beijing Cooperate Pharmaceutical Co.,Ltd

website:http://www.cooperate-pharm.com/

Contact:86-01060279497

Address:No.507,Building 4,Tianhua Street, Biomedicine industrial Base
SuZhou LaiTeou

Contact:+86-0512-88957371

Address:shanghai

Relevant to this article

Synthesis and structure-activity relationship of thiobarbituric acid derivatives as potent inhibitors of urease

Doi:10.1016/j.bmc.2014.05.057
(2014)
Design, synthesis and biological evaluation of WC-9 analogs as antiparasitic agents

Doi:10.1016/j.ejmech.2013.09.009
(2013)
Porphyrin Donor and Tunable Push–Pull Acceptor Conjugates—Experimental Investigation of Marcus Theory

Doi:10.1002/chem.201700043
(2017)
Electron-rich N-heterocyclic silylene (NHSi)-iron complexes: Synthesis, structures, and catalytic ability of an isolable hydridosilylene-iron complex

Doi:10.1021/ja402480v
(2013)
Reversible phase transition of 4-ethoxybenzenammonium iodide

Doi:10.1002/zaac.201200406
(2013)
Salt Effects on Proton Transfer from Nitrophenols to Amine or Pyridine Bases in Acetonitrile

Doi:10.1021/j100045a020
(1995)

Article Doi