
Tetrahedron Asymmetry p. 961 - 966 (1995)
Update date:2022-08-03
Topics:
Oikawa, Masato
Kusumoto, Shoichi
An efficient synthesis of three homochiral β-hydroxy fatty acid derivatives, which have been utilized in our total synthesis of lipid A, is reported.The synthesis features Sharpless asymmetric dihydroxylation of an unsaturated ester, regioselective conversion of a diol into acyloxy chlorides, and a reductive removal of the chloro group.
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(1967)