Asymmetric Intramolecular Rauhut-Currier Reaction and Its Desymmetric Version via Double Thiol/Phase-Transfer Catalysis

DOI: 10.1021/acs.joc.0c01293

Source and publish data:

Journal of Organic Chemistry p. 10760 - 10771 (2020)

Update date:2022-07-30

Topics:

Authors:

Chen, Ying-Chun

Du, Wei Du, Wei

He, Qing

Jiang, Ying

Yang, Yang

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/acs.joc.0c01293

An asymmetric intramolecular Rauhut-Currier reaction of linear bis(enones) has been achieved via double activation catalysis of thiols and phase transfer substances, furnishing both enantioenriched cyclohexene and cyclopentene derivatives (up to 95% ee).

Full text of DOI:10.1021/acs.joc.0c01293

Products guided by the article

Product name:(R)-2-(2-(4-bromobenzoyl)cyclopent-2-en-1-yl)-1-(4-bromophenyl)ethanone

Cas No:1432438-45-3

R&D Labs maybe for 1432438-45-3

Sinoway International (Jiangsu) Co., Ltd.

Contact:+86-25-86630167

Address:17 Beijing Road (West), Nanjing, China
Shandong Jincheng Zhonghua Bio-pharmaceutical Co.,Ltd

Contact:+86-533-5415882

Address:Zichuan Economic Development Zone,Zibo City,Shandong Province,China
EnBridge PharmTech Co., Ltd.

website:http://www.enbridgepharm.com

Contact:+86-510-83591909

Address:Huishan Zone, Wuxi City, Jiangsu Province, P.R.China
Dalian Synco Chemical Co., Ltd.

Contact:+86-411-83635150

Address:Rm 1004, 24, Tangshan Street, Dalian
Shanghai Hanshare Industry Co.,Ltd.

Contact:86 21 20960688

Address:RM902-903,Building E, Wanda Plaza,No.26,Zhoukang Road, Pudong District, Shanghai, China

Relevant to this article

A Novel Type of Chiral Diphosphine Ligand, trans-2,3-Bis(diphenylphosphino)-1-methyl-1-cyclopropanecarboxylic Acid and Asymmetric Allylic Alkylation by the Use of Its Palladium Complex

Doi:10.1246/cl.1992.547
(1992)
Hypervalent iodine catalyzed hofmann rearrangement of carboxamides using oxone as terminal oxidant

Doi:10.1021/jo302375m
(2012)
Design, structural and spectroscopic elucidation, and the in vitro biological activities of new diorganotin dithiocarbamates

Doi:10.1016/j.ejmech.2012.10.021
(2012)
"All-water" chemistry of tandem N-alkylation-reduction- condensation for synthesis of N-arylmethyl-2-substituted benzimidazoles

Doi:10.1039/c2gc36377a
(2012)
6,7-Dihydroxy-1-oxoisoindoline-4-sulfonamide-containing HIV-1 integrase inhibitors

Doi:10.1016/j.bmcl.2012.10.088
(2012)
Copper-mediated radical cross-coupling reaction of 2,2-dichloro-1,1,1- trifluoroethane (HCFC-123) with phenols or thiophenols

Doi:10.1021/ol302962p
(2012)

Article Doi