A Novel Type of Chiral Diphosphine Ligand, trans-2,3-Bis(diphenylphosphino)-1-methyl-1-cyclopropanecarboxylic Acid and Asymmetric Allylic Alkylation by the Use of Its Palladium Complex

DOI: 10.1246/cl.1992.547

Source and publish data:

Chemistry Letters p. 547 - 550 (1992)

Update date:2022-07-30

Topics: Asymmetric Allylic Alkylation Palladium complex

Authors:

Okada, Yoshiharu

Minami, Toru

Yamamoto, Tsutomu

Ichikawa, Junji

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Article abstract of DOI:10.1246/cl.1992.547

Optically active trans-2,3-bis(diphenylphosphino)-1-methyl-1-cyclopropanecarboxylic acid was synthesized from trans-1,2-bis(diphenylphosphinyl)ethene via resolution of the racemic diphosphine oxide.Asymmetric allylic alkylation of 2-cyclohexenyl acetate w

Full text of DOI:10.1246/cl.1992.547

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