A New Selective Method for the Homolytic Alkylation and Carboxylation of Quinones by Monoesters of Oxalic Acid

DOI: 10.1246/cl.1992.1299

Source and publish data:

Chemistry Letters p. 1299 - 1302 (1992)

Update date:2022-09-26

Topics: Quinones Carboxylation Experimental terms

Authors:

Coppa, Fausta

Fontana, Francesca

Lazzarini, Edoardo

Minisci, Francesco

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1992.1299

Alkyl and alkoxycarbonyl radicals were generated by oxidative decarboxylation of oxalic acid monoesters by persulfate; they were then utilized for the selective substitution of quinones.

Full text of DOI:10.1246/cl.1992.1299

Products guided by the article

Product name:2-Naphthalenecarboxylic acid, 1,4-dihydro-1,4-dioxo-, cyclohexyl ester

Cas No:143427-17-2

R&D Labs maybe for 143427-17-2

Shanghai united Scientific Co.,Ltd.

Contact:+86-21-53535353

Address:28F No.900 huaihai Road Shanghai China
Shanghai Gsyn Chemical Co.,Ltd.

Contact:86-021-67158290

Address:86-021-67158291
Nanjing Vincero International Trading Co.,Ltd

Contact:8618936897229

Address:NO.68, ZhuShan Road, JiangNing WanDa Plaza, Building E Room 1703
SHIJIAZHUANG CHENSHI IMPORT AND EXPORT CO.,LTD

Contact:+86-311-89871056

Address:RM2017 BUILDING CTIANSHAN GALAXY PLAZA,NO168 CHANGJIANG ROAD,GAOXIN DISTRICT,SHIJIAZHUANG CITY, HEBEI,CHINA
Weifang Ocean Trading Co., Ltd.

Contact:+86-536-2081155

Address:Room2606, Yuqing Building, 518#, Yuquan Road, High-tech Development Zone, Weifang City, Shandong Province, China

Relevant to this article

Extensive Chlorination of Methylnaphthalenes, Friedel-Crafts Alkylation of Pentachlorobenzene by Heptachloro(chloromethyl)naphthalenes, and Related Results

Doi:10.1021/jo00047a026
(1992)
In Situ Formation of Vinylboranes for Use in Diels-Alder Reactions. An Easy One-Pot Diels-Alder Synthesis of Cyclohexanols

Doi:10.1021/jo00047a037
(1992)
Syntheses of All Four Stereoisomers Which Are Conformationally Constrained 1,4-Dioxanyl Analogs of the Antineoplastic Ether Lipid ET-18-OCH3

Doi:10.1021/jo00049a021
(1992)
Targeting the Hsp90 chaperone: Synthesis of novel resorcylic acid macrolactone inhibitors of Hsp90

Doi:10.1002/chem.200902766
(2010)
Reaction of Azoalkanes with Isolable Cation Radical Salts

Doi:10.1021/jo00049a025
(1992)
Enantioselective synthesis of 2,2-dialkyltetrahydropyran-3-ones via the asymmetric Michael addition reaction using chiral imines

Doi:10.1016/S0957-4166(00)82185-0
(1992)

Article Doi