Continued search for elusive persistent trivalent organosilyl cations: The claimed trimethylsilyl cation revisited. Attempted preparation of cyclic and halogen-bridged organosilicenium ions

DOI: 10.1021/ja00046a020

Source and publish data:

Journal of the American Chemical Society p. 7737 - 7742 (1992)

Update date:2022-09-26

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Authors:

Olah, George A.

Rasul, Golam

Heiliger, Ludger

Bausch, Joseph

Surya Prakash

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Article abstract of DOI:10.1021/ja00046a020

Comparison of ab initio/IGLO calculated ¹H, ¹³C, and ²⁹Si NMR chemical shifts with the experimental data on trimethylsilyl perchlorete and related derivatives supports the conclusion that no long-lived persistent trimethyl

Full text of DOI:10.1021/ja00046a020

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