A Short Synthesis of (+/-) N-Benzyl Aspidospermidine

DOI: 10.1016/0040-4039(92)88084-I

Source and publish data:

Tetrahedron Letters p. 4001 - 4004 (1992)

Update date:2022-08-03

Topics: Enantioselective Nucleophile Electrophile Organic synthesis Diastereoselective N-Benzyl Chiral synthesis Palladium-catalyzed coupling Diastereomeric

Authors:

Benchekroun-Mounir, Nora

Dugat, Denise

Gramain, Jean-Claude

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Article abstract of DOI:10.1016/0040-4039(92)88084-I

(+/-) N-Benzyl aspidospermidine is synthesized in seven steps via the trisubstituted hexahydrocarbazolone 4; reductive cyclization of this intermediate which is obtained by photocyclization and Michael reaction with nitroethylene, creates simulteanously b

Full text of DOI:10.1016/0040-4039(92)88084-I

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