A Short Synthesis of (+/-) N-Benzyl Aspidospermidine

DOI: 10.1016/0040-4039(92)88084-I

Source and publish data:

Tetrahedron Letters p. 4001 - 4004 (1992)

Update date:2022-08-03

Topics: Enantioselective Nucleophile Electrophile Organic synthesis Diastereoselective N-Benzyl Chiral synthesis Palladium-catalyzed coupling Diastereomeric

Authors:

Benchekroun-Mounir, Nora

Dugat, Denise

Gramain, Jean-Claude

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(92)88084-I

(+/-) N-Benzyl aspidospermidine is synthesized in seven steps via the trisubstituted hexahydrocarbazolone 4; reductive cyclization of this intermediate which is obtained by photocyclization and Michael reaction with nitroethylene, creates simulteanously b

Full text of DOI:10.1016/0040-4039(92)88084-I

Products guided by the article

Product name:(4R,6aR,11bR)-7-Benzyl-4-(3-chloro-propyl)-4-ethyl-2,4,5,6,6a,7-hexahydro-1H-pyrrolo[2,3-d]carbazole

Cas No:143466-46-0

R&D Labs maybe for 143466-46-0

Suzhou Health Chemicals Co., Ltd.

website:http://www.healthchems.com

Contact:13776257979

Address:No. 338, Jingang Avenue,
HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.

Contact:+86-186-02659358

Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China
Huangshan Violet Biological Technology Co., Ltd

Contact:+86-559-2335676

Address:16-201 JinShanYuan,JiangNan New City,TunXi District,HuangShan City,AnHui Province,China
Beijing Pure Chem Co.,Ltd.

Contact:+86-10-83993285

Address:Rm.1708, Haobai Tower, Building 6, No.50, North Road, West Third Ring, Haidian District, Beijing, China
Dalian Synco Chemical Co., Ltd.

Contact:+86-411-83635150

Address:Rm 1004, 24, Tangshan Street, Dalian

Relevant to this article

Rhodium(III)-catalyzed oxidative ciH coupling of N-methoxybenzamides with aryl boronic acids: One-pot synthesis of phenanthridinones

Doi:10.1002/anie.201206890
(2012)
Functionalized orthoesters as powerful building blocks for the efficient preparation of heteroaromatic bicycles

Doi:10.1021/ol301472a
(2012)
Doi:10.1007/BF03343970
()
Dis-assembly of a benzylic CF₃ group mediated by a niobium(III) imido complex

Doi:10.1021/ja4033007
(2013)
4-(1H-Imidazo[4,5-f]-1,10-phenanthrolin-2-yl)phenol-based G-quadruplex DNA binding agents: Telomerase inhibition, cytotoxicity and DNA-binding studies

Doi:10.1016/j.bmc.2012.11.059
(2013)
Triflimide: An Overlooked High-Performance Catalyst of the Mukaiyama Aldol Reaction of Silyl Ketene Acetals with Ketones

Doi:10.1002/chem.201803142
(2018)

Article Doi