Stereoselective Nucleophilic Additions to Trialkylsilyl-Substituted Acyclic Acetals

DOI: 10.1021/jo00045a016

Source and publish data:

Journal of Organic Chemistry p. 5078 - 5080 (1992)

Update date:2022-09-26

Topics:

Authors:

Linderman, Russell J.

Anklekar, Tarakeshwar V.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00045a016

Regioselective and diastereoselective Mukaiyama-type aldol reactions of silyl-substituted mixed acyclic acetals provide the aldol products with 5:1 to 14:1 selectivity.

Full text of DOI:10.1021/jo00045a016

Products guided by the article

Product name:3-(1-tert-Butyl-hexyloxy)-1-phenyl-butan-1-one

Cas No:143471-47-0

R&D Labs maybe for 143471-47-0

Chengda Pharmaceuticals Co., Ltd.

Contact:+86-573-84601188

Address:hengshan Road 5# in Jiashan, zhejiang
Hangzhou Showland Technology Co., Ltd.

Contact:86-571-88920516

Address:ROOM2118,NO.553,WENSAN ROAD,HANGZHOU,CHINA
Chongqing Rong＆Quan Pharmaceutical Technology Co. , Ltd.

Contact:86-023-65268721

Address:No. 7, Manshanhong Village, Pingdingshan, Shapingba District, Chongqing Province, China
Beijing Cooperate Pharmaceutical Co.,Ltd

website:http://www.cooperate-pharm.com/

Contact:86-01060279497

Address:No.507,Building 4,Tianhua Street, Biomedicine industrial Base
Shanghai Zhihua ChemTech Co., Ltd.

Contact:+86-13774313779

Address:Room 817 Suite B 3333 Shenjiang Road

Relevant to this article

The orientation of the β-hydroxyl group controls the diastereoselectivity during the hydride reduction and Grignard reaction of inososes

Doi:10.1016/j.tet.2013.04.081
(2013)
An iterative, facile stereoselective synthesis of C1-C11 fragment of borrelidin via enzymatic desymmetrization strategy

Doi:10.1039/c3ra22754e
(2013)
Anomalous reactions of triphenylchlorosilane with metal carbonyl anions

Doi:10.1021/ic50110a029
(1972)
Catalytic conversions of diazosugars

Doi:10.1016/S0040-4039(02)02407-3
(2002)
New insights into the synthesis and characterization of 2-methoxy-3-alkylpyrazines and their deuterated isotopologues

Doi:10.1002/jlcr.1888
(2011)
Reversal of stereochemistry in a two-step Staudinger reaction by changing the backbone protecting group. Synthesis of NH-trans-3-benzoyloxy-4-aryl-azetidinones

Doi:10.1016/S0040-4039(99)01800-6
(1999)

Article Doi