Stereoselective Nucleophilic Additions to Trialkylsilyl-Substituted Acyclic Acetals

DOI: 10.1021/jo00045a016

Source and publish data:

Journal of Organic Chemistry p. 5078 - 5080 (1992)

Update date:2022-09-26

Topics:

Authors:

Linderman, Russell J.

Anklekar, Tarakeshwar V.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00045a016

Regioselective and diastereoselective Mukaiyama-type aldol reactions of silyl-substituted mixed acyclic acetals provide the aldol products with 5:1 to 14:1 selectivity.

Full text of DOI:10.1021/jo00045a016

Products guided by the article

Product name:3-(1-tert-Butyl-hexyloxy)-1-phenyl-butan-1-one

Cas No:143471-47-0

R&D Labs maybe for 143471-47-0

Tianjin Tensing Fine Chemical Research Develop Centre

Contact:86-022-23718576,13032267585

Address:2-2-201,13 Guiyuan road,Huayuan Industry district,Tianjin,china
Allright GC (Jinan) Biotechnology Ltd.

website:https://www.argcbiotech.com/

Contact:86-18405413579-

Address: No.27566 of Jingshiroad, Huaiyin District, Jinan City(250011), Shandong Province, China.
Nanjing Chemipioneer Pharma&Tech Co.,Ltd

website:http://www.chemipioneer.com.cn

Contact:+86-25-52685700

Address:Room 305，A Block，Biological-Medicine Building，Business Start-up Center，Xin-ke 1st Road, High-tech development zone，Nanjing city，Jiangsu Province, China
HuiFeiChem PharmaTech Co.Ltd

Contact:0510-85393305

Address:1619 Huishan Avenue, Huishan District, Wuxi,
Shanghai Sungo Technology Chemical Co., Ltd

Contact:0086-21-51385579

Address:Room2010, F/20, Tonghua Plaza, NO 345 Jinxiang Road, Jinqiao Export Processing Zone, Shanghai, 201206 P.R.CHINA

Relevant to this article

The orientation of the β-hydroxyl group controls the diastereoselectivity during the hydride reduction and Grignard reaction of inososes

Doi:10.1016/j.tet.2013.04.081
(2013)
An iterative, facile stereoselective synthesis of C1-C11 fragment of borrelidin via enzymatic desymmetrization strategy

Doi:10.1039/c3ra22754e
(2013)
Anomalous reactions of triphenylchlorosilane with metal carbonyl anions

Doi:10.1021/ic50110a029
(1972)
Catalytic conversions of diazosugars

Doi:10.1016/S0040-4039(02)02407-3
(2002)
New insights into the synthesis and characterization of 2-methoxy-3-alkylpyrazines and their deuterated isotopologues

Doi:10.1002/jlcr.1888
(2011)
Reversal of stereochemistry in a two-step Staudinger reaction by changing the backbone protecting group. Synthesis of NH-trans-3-benzoyloxy-4-aryl-azetidinones

Doi:10.1016/S0040-4039(99)01800-6
(1999)

Article Doi