A Facile Synthesis of Trifluoromethylamines by Oxidative Desulfurization-Fluorination of Dithiocarbamates

DOI: 10.1016/S0040-4039(00)74682-X

Source and publish data:

Tetrahedron Letters p. 4177 - 4178 (1992)

Update date:2022-08-03

Topics:

Authors:

Kuroboshi, Manabu

Hiyama, Tamejiro

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Article abstract of DOI:10.1016/S0040-4039(00)74682-X

Reaction of methyl dithiocarbamates R1R2N-C(S)SMe with n-Bu4N(1+)H2F3(1-) and N-bromosuccinimde provides trifluoromethylamines R1R2N-CF3 in good yields. Key Words: oxidative desulfurization-fluorination; dithiocarbamates; trifluoromethylamine

Full text of DOI:10.1016/S0040-4039(00)74682-X

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