Oxidative desulfurization-fluorination of xanthates. A convenient synthesis of trifluoromethyl ethers and difluoro (methylthio)methyl ethers

DOI: 10.1016/S0040-4039(00)74681-8

Source and publish data:

Tetrahedron Letters p. 4173 - 4176 (1992)

Update date:2022-09-26

Topics:

Authors:

Kuroboshi, Manabu

Suzuki, Kazundo

Hiyama, Tamejiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)74681-8

Treatment of xanthates R-OC(S)SMe with (HF)₉/Py and 1,3-dibromo-5,5-dimethylhydantoin gives trifluoromethyl ethers R-OCF₃ through intermediates R-OCF₂SMe, which could be isolated upon treatment of xanthates with n-Bu₄N⁺H₂F₃^- and N-bromosuccinimide.

Full text of DOI:10.1016/S0040-4039(00)74681-8

Products guided by the article

Product name:Benzene, 1-[difluoro(methylthio)methoxy]-4-propyl-

Cas No:143582-91-6

R&D Labs maybe for 143582-91-6

Jinan Jiaquan Chemical Co.,Ltd

Contact:+86-531-62318366

Address:Room 502 of Yidonghuayuan No.601 Huaxin Road Licheng District Jinan China
Zibo Jujin Chemical Industry Co., Ltd.（Dongming Jujin Chemical Industry Co., Ltd. ）

Contact:+86-533-2975022

Address:No.99 Shanquan Road, Zhangdian District
guide(suzhou) fine materials co. ltd

Contact:0512-80972173

Address:21st Building, No.369 Lushan Rd, New District Suzhou China 215129
Hubei Xiangxi Chemical Industry Co.,Ltd

Contact:+86-710-3454830

Address:No.7, Daqing East Road, Xiangfan City, Hubei Province, China
Shanghai ZaiQi Bio-Tech Co., Ltd.,

Contact:+86-21-5482 4098

Address:Bldg. No.7, No.201 MinYi Rd，Songjiang CaoHeJing High-Tech Park Shanghai 201516 P,R,China

Relevant to this article

A universal flow cytometry assay for screening carbohydrate-active enzymes using glycan microspheres

Doi:10.1039/c3cc39155h
(2013)
Synthesis and antibacterial evaluation of furan derivatives bearing a rhodanine moiety

Doi:10.1007/s00044-013-0648-7
(2014)
Synthesis, antimicrobial, antiquorum-sensing, antitumor and cytotoxic activities of new series of fused [1,3,4]thiadiazoles

Doi:10.1016/j.ejmech.2013.02.010
(2013)
Synthesis of a novel 1,2-dithianenucleoside via Pummerer-like reaction, followed by Vorbruggen glycosylation between a 1,2-dithiane derivative and uracil

Doi:10.1039/c3cc44848g
(2013)
Palladium catalyzed cyclizations of oxime esters with 1,2-disubstituted alkenes: Synthesis of dihydropyrroles

Doi:10.1021/ol4023112
(2013)
Dihydropyrromethenones by Pd(0)-Mediated Coupling of Iodopyrroles and Acetylenic Amides. Synthesis of the A,B-Ring Segment of Phytochrome

Doi:10.1021/jo970289b
(1997)

Article Doi