Tetrahedron Letters p. 3613 - 3616 (1992)
Update date:2022-07-29
Topics:
Denenmark, Daniella
Winkler, Tammo
Waldner, Adrian
Mesmaeker, Alain De
The radical translocation reactions in N,N-disubstituted acetamides 10a, 14a - d and trifluoroacetamides 10b, 14e - f have been studied by deuteration experiments with n-Bu3SnD.The intramolecular hydrogen atom transfer from the N-alkyl side chain to the aryl radical takes place through competing 6-, 7-, 8-membered transition states.
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