The Synthesis and Complete 1H and 13C NMR Spectral Assignment of 2,2,4,4,6,6-Hexanitroadamantane and its Precursor Nitroketones by 2D NMR Spectroscopy

Article abstract of DOI:10.1016/S0040-4020(01)90175-9

The synthesis of 2,2,4,4,6,6-hexanitroadamantane from the precursors 4,4,6,6-tetranitroadamantan-2-one and 4,4-dinitroadamantane-2,6-dione is reported.The complete 1H and 13C NMR assignment of these compounds by 2D 13C-1H shift correlated spectra. 1H-1H COSY spectra and 1H-1H NOESY spectra is described.