Atropisomerism in a Molecular Gear, 8-Bromo-1,4-dimethyl-9-(2-methylbenzyl)triptycene

DOI: 10.1246/cl.1990.1373

Source and publish data:

Chemistry Letters p. 1373 - 1376 (1990)

Update date:2022-07-30

Topics:: Authors:

Yamamoto, Gaku

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Article abstract of DOI:10.1246/cl.1990.1373

Two rotamers, ap and sc1, of the title compound were separately isolated as stable entities at room temperature.The rotamers gave an equilibrium mixture of the two at elevated temperatures, K(/) being 2.26 at 60 deg C in toluene-d8.The kinetic pa

Full text of DOI:10.1246/cl.1990.1373

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Atropisomerism in a Molecular Gear, 8-Bromo-1,4-dimethyl-9-(2-methylbenzyl)triptycene

DOI: 10.1246/cl.1990.1373

Source and publish data:

Authors:

Article abstract of DOI:10.1246/cl.1990.1373

Full text of DOI:10.1246/cl.1990.1373

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