Stereoselective Synthesis of 1,2-cis-Arabinofuranosides Using a New Titanium Catalyst

Article abstract of DOI:10.1246/cl.1992.1401

In the presence of catalytic amounts of <1,2-benzenediolato(2-)-O,O'>oxotitanium and trimethylsilyl triflate, 1-O-trimethylsilyl-2,3,5-tri-O-benzyl-D-arabinofuranose stereoselectively reacts with various trimethylsilyl ethers to afford the corresponding 1