Effect of solvent polarity extremes on the coupling of cyclopropylcarbene-chromium complexes and alkynes: Synthesis of β-alkoxycyclopentadienones, 2-cyclopentene-1,3-diones, and cis 4,5-disubstituted cyclopentenones

DOI: 10.1016/S0040-4039(96)02282-4

Source and publish data:

Tetrahedron Letters p. 59 - 62 (1997)

Update date:2022-09-26

Topics:

Authors:

Herndon, James W.

Patel, Paren P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(96)02282-4

The reaction between acetylenes and cyclopropylcarbene-chromium complexes in hexane affords exclusively cyclopentadienone derivatives in good yield, which are readily hydrolyzed to cyclopentenediones. The analogous reaction in 50:50 water dioxane affords cis disubstituted cyclopentenones.

Full text of DOI:10.1016/S0040-4039(96)02282-4

Products guided by the article

Product name:cis-4,5-dipropyl-3-methoxy-2-cyclopentenone

Cas No:144193-50-0

R&D Labs maybe for 144193-50-0

Jining tiansheng chemical co.,ltd.

Contact:+86-537-5158722

Address:ROOM 1011, BLOCK B, CUIDU INTERNATIOAL BUSINESS CENTER, JINING CITY, CHINA
Nanjing Duly Biotech Co., Ltd

website:http://www.dulynet.com/

Contact:025-84699383 -8003

Address:Room 503, Building 2, Chuangxinhui, No. 61 Wenjing Road, High-tech Development Zone, Pukou District, Nanjing City, Jiangsu Province Nanjing, Jiangsu
Shanghai Rainbow Chemistry Co., Ltd.

Contact:+86-21-64968086-5815/5812

Address:3rd floor, Building 7, 251 Faladi Road, Zhangjiang Hi-Tech Park, Pudong District, Shanghai, P.R. China
Guangzhou Probig Fine Chemical Co., Ltd.

Contact:020-86297874

Address:No.2, 1/F, No.20, Hetai Road,Hebian Village, Baiyun District,Guangzhou,China
Jinan Kaypharm Chemical Co.,Ltd

Contact:86-0531-86986780

Address:Room101,No189-2,Huayuan Road,Jinan City,Shandong Province

Relevant to this article

Dendritic fluoroalcohols as catalysts for alkene epoxidation with hydrogen peroxide

Doi:10.1002/anie.201206003
(2013)
Perlite–SO₃H nanoparticles: very efficient and reusable catalyst for three-component synthesis of N-cyclohexyl-3-aryl-quinoxaline-2-amine derivatives under ultrasound irradiation

Doi:10.1007/s13738-018-1426-8
(2018)
Ruthenium-catalyzed aerobic oxidative cyclization of aromatic and heteroaromatic nitriles with alkynes: A new route to isoquinolones

Doi:10.1039/c3cc42683a
(2013)
Nickel(0)-promoted Synthesis of Tetralin Lactones from the Co-cyclisation of Monoynes and Octa-1,7-diynes Terminally Substituted with Ester or Amide Groups

Doi:10.1039/P19920002163
(1992)
Polycylopentadienyls: synthesis of arylsilylcyclopentadienyl compounds and their η⁵-complexes with tungsten

Doi:10.1016/0022-328X(92)83456-R
(1992)
Synthesis and cytotoxicity evaluation of some novel 1-(3-Chlorophenyl) piperazin-2-one derivatives bearing imidazole bioisosteres

Doi:10.1071/CH13031
(2013)

Article Doi