Journal of the Chemical Society. Chemical communications p. 1060 - 1062 (1992)
Update date:2022-08-02
Topics:
Araki, Koji
Kuboki, Takashi
Yamada, Masaki
Shiraishi, Shinsaku
Exclusive formation of amino acid esters took place at an appreciable rate in the CuII-catalysed solvolysis of 6,6'-(α-alanylamino or α-phenylalanylamino)-2,2'-bipyridine in alcohol-borate buffer (pH 7.2) solutions at 20 deg C via formation of an amide-O-coordinated complex, even though appreciable amounts of water (0-40percent v/v) were present in the solution.
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