16-Electron Half-sandwich Ru(II)-Thiolate Complexes, Ru(SAr)2(η6-p-cymene) (Ar = 2,6-dimethylphenyl and 2,4,6-triisopropylphenyl)

DOI: 10.1246/cl.1992.1473

Source and publish data:

Chemistry Letters p. 1473 - 1476 (1992)

Update date:2022-09-26

Topics:

Authors:

Mashima, Kazushi

Mikami, Aki

Nakamura, Akira

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Article abstract of DOI:10.1246/cl.1992.1473

Treatment of 2 with sodium 2,6-dimethylbenzenethiolate or sodium 2,4,6-triisopropylbenzenethiolate in methanol afforded a mononuclear five-coordinated ruthenium thiolate complex, Ru(SAr)2(p-cymene) (2a: Ar = 2,6-dimethylphenyl; 2b: 2,4,6-triisopropylphenyl), whose structure is determined by X-ray analysis of 2a.

Full text of DOI:10.1246/cl.1992.1473

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