Radical-induced epoxide fragmentation chemistry. Atom transfer cyclization of iodoepoxides to cyclopentanols

DOI: 10.1016/S0040-4039(00)61259-5

Source and publish data:

Tetrahedron Letters p. 4687 - 4690 (1992)

Update date:2022-08-16

Topics:

Authors:

Rawal Rawal

Iwasa Iwasa

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Article abstract of DOI:10.1016/S0040-4039(00)61259-5

Iodoepoxides, formed by the reaction of PhI(OAc)₂ and I₂ with an allylic alcohol, can be rearranged to cis-fused bicyclic compounds using catalytic amounts of (n-Bu₃Sn)₂ and AIBN. Formally an atom transfer cycli

Full text of DOI:10.1016/S0040-4039(00)61259-5

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