Tetrahedron p. 7149 - 7156 (1992)
Update date:2022-08-03
Topics:
Kitamura
Furuki
Taniguchi
Stang
A reagent [PhIO-TfOH] prepared by mixing iodosylbenzene and triflic acid undergoes electropholic addition to various alkynes under mild conditions. The addition is a highly stereoselective anti-addition and provides (E)-[β-(trifluoromethanesulfonyloxy)vinyl]iodonium triflates in good to high yields.
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