Tandem pericyclic reactions. The first X-ray structure of an initial pyrone-olefin adduct and an easy, stereocontrolled, entry into polyoxygenated cyclohexanes

DOI: 10.1016/S0040-4039(00)61170-X

Source and publish data:

Tetrahedron Letters p. 5649 - 5652 (1992)

Update date:2022-08-05

Topics:

Authors:

Marko Marko

Seres Seres

Swarbrick

Staton Staton

Adams Adams

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Article abstract of DOI:10.1016/S0040-4039(00)61170-X

Under high-pressure conditions, 2-pyrone undergoes Diels-Alder reaction with a variety of dienophiles, leading to isolable, bridged, bicyclic lactones. The first X-Ray structure of one of these lactones and its conversion into polyoxygenated cyclohexane d

Full text of DOI:10.1016/S0040-4039(00)61170-X

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