Functionality transfer from C8 to C9 in sesquiterpenes. Synthesis of the named Herbolide E from artemisin

DOI: 10.1016/S0040-4039(00)79147-7

Source and publish data:

Tetrahedron Letters p. 5253 - 5256 (1992)

Update date:2022-08-05

Topics:

Authors:

Blay, Gonzalo

Cardona, Luz

Garcia, Begona

Pedro, Jose R.

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Article abstract of DOI:10.1016/S0040-4039(00)79147-7

The key intermediate 6 was obtained in five steps from artemisin (1). The spectroscopic characteristics of the synthetic product 7a reveal that the proposed structure for the natural herbolide E must be revised.

Full text of DOI:10.1016/S0040-4039(00)79147-7

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