Magnesium trifluoromethanesulfonimide(triflimide) promoted substitution reactions of allylic and benzylic acetates. Magnesium triflimide as a substitute for magnesium perchlorate.

DOI: 10.1016/S0040-4039(97)00441-3

Source and publish data:

Tetrahedron Letters p. 2645 - 2648 (1997)

Update date:2022-08-04

Topics:

Authors:

Grieco, Paul A.

Handy, Scott T.

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Article abstract of DOI:10.1016/S0040-4039(97)00441-3

Magnesium triflimide(10 mol% in methylene chloride) is a convenient catalyst for the nucleophilic substitution of allylic and benzylic acetates, and constitutes a useful alternative to magnesium perchlorate.

Full text of DOI:10.1016/S0040-4039(97)00441-3

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