Magnesium trifluoromethanesulfonimide(triflimide) promoted substitution reactions of allylic and benzylic acetates. Magnesium triflimide as a substitute for magnesium perchlorate.

DOI: 10.1016/S0040-4039(97)00441-3

Source and publish data:

Tetrahedron Letters p. 2645 - 2648 (1997)

Update date:2022-08-04

Topics:

Authors:

Grieco, Paul A.

Handy, Scott T.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)00441-3

Magnesium triflimide(10 mol% in methylene chloride) is a convenient catalyst for the nucleophilic substitution of allylic and benzylic acetates, and constitutes a useful alternative to magnesium perchlorate.

Full text of DOI:10.1016/S0040-4039(97)00441-3

Products guided by the article

Product name:Cyclohexene, 1,5,5-trimethyl-3-(2-propenyl)-

Cas No:144650-13-5

R&D Labs maybe for 144650-13-5

Hisyntech Corporation Limited

Contact:0086-22-23410962

Address:17-201, Ningfuli, Shuishanggongyuandong road,Nankai district, Tianjin, China
Shijiazhuang City Xiehe Pharmaceutical Co., Ltd

Contact:+86-311-80817929

Address:Shangzhuang,Shijiazhuang,China
Shochem(Shanghai) Co., Ltd

website:http://www.shochem.com

Contact:021-50800795

Address:No.1043, Halei Rd, Zhangjiang Hi-Tech Park, Shanghai, Postcode 201203, China
Shanghai WinTide BioTechnology Co.,Ltd

Contact:86-21-37100630

Address:No. 908 Yunhe Road, Fengxian district, Shanghai
Chongqing maohuan Chemicals Co., Ltd

website:http://www.bschem.com

Contact:+86 13996103726

Address:Chongqing Nan'an District Tu Town

Relevant to this article

Synthesis and antiprotozoal activity of nitazoxanide-N-methylbenzimidazole hybrids

Doi:10.1016/j.bmcl.2013.10.011
(2013)
Catalytic asymmetric hydrophosphonylation of ketimines

Doi:10.1021/ja4059316
(2013)
Reaction of isatoic anhydride, amine, and N,N′-dialkyl carbodiimides under solvent-free conditions: New and efficient synthesis of 3-alkyl-2-(alkylamino) quinazolin-4(3H)-ones

Doi:10.1080/00397911.2012.714042
(2013)
Mesoporous nanocrystalline MgAl₂O₄: A new heterogeneous catalyst for the synthesis of 2,4,6-triarylpyridines under solvent-free conditions

Doi:10.2478/s11696-013-0361-5
(2013)
Synthesis, biological evaluation, X-ray molecular structure and molecular docking studies of RGD mimetics containing 6-amino-2,3-dihydroisoindolin-1-one fragment as ligands of integrin α_iIbβ₃

Doi:10.1016/j.bmc.2013.05.019
(2013)
Synthesis of arylbenziodoxoles using pseudocyclic benziodoxole triflate and arenes

Doi:10.24820/ARK.5550190.P011.324
(2020)

Article Doi