Magnesium trifluoromethanesulfonimide(triflimide) promoted substitution reactions of allylic and benzylic acetates. Magnesium triflimide as a substitute for magnesium perchlorate.

DOI: 10.1016/S0040-4039(97)00441-3

Source and publish data:

Tetrahedron Letters p. 2645 - 2648 (1997)

Update date:2022-08-04

Topics:

Authors:

Grieco, Paul A.

Handy, Scott T.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)00441-3

Magnesium triflimide(10 mol% in methylene chloride) is a convenient catalyst for the nucleophilic substitution of allylic and benzylic acetates, and constitutes a useful alternative to magnesium perchlorate.

Full text of DOI:10.1016/S0040-4039(97)00441-3

Products guided by the article

Product name:Cyclohexene, 1,5,5-trimethyl-3-(2-propenyl)-

Cas No:144650-13-5

R&D Labs maybe for 144650-13-5

Weifang Dongxing Chitosan Factory

website:http://dxchitosan.lookchem.com/

Contact:13475651157

Address:Weifang city ,shandong province
suzhou chukai pharmateach co,.ltd

website:http://www.chukaipharma.com/

Contact:86-512-888125066

Address:Building 3, Wujiang Scientific Innovation Park, 2358 Changan Rd, Wujiang 215200, Jiangsu Province, P. R. China
Liaoning Yufeng Chemical Co.,Ltd.

Contact:86-0419-3418888

Address:The metallurgical industrial zone,shoushan town, Liaoyang, Liaoning, China
Suqian Ruixing Chemical Co., Ltd.

Contact:+86-527-80805666（总机）;84836008(销售)

Address:3 Jingsilu, Zone north, Hubin Xincheng Development Park, Suqian, China
KODI CHEMICAL CO., LTD

Contact:021

Address:Pudong

Relevant to this article

Synthesis and antiprotozoal activity of nitazoxanide-N-methylbenzimidazole hybrids

Doi:10.1016/j.bmcl.2013.10.011
(2013)
Catalytic asymmetric hydrophosphonylation of ketimines

Doi:10.1021/ja4059316
(2013)
Reaction of isatoic anhydride, amine, and N,N′-dialkyl carbodiimides under solvent-free conditions: New and efficient synthesis of 3-alkyl-2-(alkylamino) quinazolin-4(3H)-ones

Doi:10.1080/00397911.2012.714042
(2013)
Mesoporous nanocrystalline MgAl₂O₄: A new heterogeneous catalyst for the synthesis of 2,4,6-triarylpyridines under solvent-free conditions

Doi:10.2478/s11696-013-0361-5
(2013)
Synthesis, biological evaluation, X-ray molecular structure and molecular docking studies of RGD mimetics containing 6-amino-2,3-dihydroisoindolin-1-one fragment as ligands of integrin α_iIbβ₃

Doi:10.1016/j.bmc.2013.05.019
(2013)
Synthesis of arylbenziodoxoles using pseudocyclic benziodoxole triflate and arenes

Doi:10.24820/ARK.5550190.P011.324
(2020)

Article Doi