Organic Letters p. 3926 - 3929 (2015)
Update date:2022-08-04
Topics: 1,3-Dicarbonyl Compounds Palladium-Catalyzed Decarboxylative coupling
Kenny, Miles
Christensen, Jeppe
Coles, Simon J.
Franckeviius, Vilius
A palladium-catalyzed chemo- and regioselective coupling of 1,3-dicarbonyl compounds via an allylic linker has been developed. This reaction, which displays broad substrate scope, forms two C-C bonds and installs two all-carbon quaternary centers. The regioselectivity of the reaction can be predictably controlled by utilizing an enol carbonate of one of the coupling partners.
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