Reaction of Diphenyl Phosphorochloridate with Amide Enolates: A New and Convenient Synthesis of 2-Monosubstituted 3-(N-Methyl-N-phenylamino)-2H-azirines

DOI: 10.1002/hlca.19920750612

Source and publish data:

Helvetica Chimica Acta p. 1866 - 1871 (1992)

Update date:2022-08-04

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Authors:

Villalgordo, Jose M.

Heimgartner, Heinz

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Article abstract of DOI:10.1002/hlca.19920750612

Reaction of diphenyl phosphorochloridate with amide enolates and subsequent treatment with NaN3 leads to 2-monosubstituted 3-amino-2H-azirines 5 in moderate yields.The reactivity of these azirines is briefly explored.

Full text of DOI:10.1002/hlca.19920750612

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