Reaction of Diphenyl Phosphorochloridate with Amide Enolates: A New and Convenient Synthesis of 2-Monosubstituted 3-(N-Methyl-N-phenylamino)-2H-azirines

DOI: 10.1002/hlca.19920750612

Source and publish data:

Helvetica Chimica Acta p. 1866 - 1871 (1992)

Update date:2022-08-04

Topics:

Authors:

Villalgordo, Jose M.

Heimgartner, Heinz

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19920750612

Reaction of diphenyl phosphorochloridate with amide enolates and subsequent treatment with NaN3 leads to 2-monosubstituted 3-amino-2H-azirines 5 in moderate yields.The reactivity of these azirines is briefly explored.

Full text of DOI:10.1002/hlca.19920750612

Products guided by the article

Product name:Benzamide, N-[1-methyl-2-(methylphenylamino)-2-thioxoethyl]-

Cas No:144691-26-9

R&D Labs maybe for 144691-26-9

Changsha Nutritopper Bio Technology Co.,Ltd.

Contact:+86-731-87803543

Address:East 1st Street, Baima Road, Ningxiang County
Weifang Arylchem Chemical Co., LTD

Contact:86-536-5217866

Address:Development Zone, Shouguang, Shandong Province
SuZhou LaiTeou

Contact:+86-0512-88957371

Address:shanghai
Jiangsu Fengshan Group Co., Ltd.

Contact:86-25-86558671

Address:1903,Central International Mansion 105-6 North Zhongshan Road, Nanjing, China
Shanghai Standard Biotech Co., Ltd.

Contact:+86-18502101150

Address:Room 103, Building 2nd, NO.720, Cailun Road , Pudong District, Shanghai, China

Relevant to this article

Synthesis of α-ketothioamides via willgerodt-kindler reaction of arylglyoxals with amines and sulfur under solvent-free conditions

Doi:10.1055/s-0032-1316897
(2013)
A stereoselective cis-enyne synthesis using vinyl sulfone chemistry

Doi:10.1016/S0040-4020(01)80456-7
(1992)
Catalytic oxidative cleavage of catechol by a non-heme iron(iii) complex as a green route to dimethyl adipate

Doi:10.1039/c3cc42423e
(2013)
Nanodomain cubic cuprous oxide as reusable catalyst in one-pot synthesis of 3-alkyl/aryl-3-(pyrrole-2-yl/indole-3-yl)-2-phenyl-2,3-dihydro-isoindolinones in aqueous medium

Doi:10.1039/c3ra46168h
(2014)
A quick route for the synthesis of 3-Aryl-3,4-dihydro-2H-benz[e]-1,3- oxazin-2-ones

Doi:10.14233/ajchem.2013.14053
(2013)
Synthesis and catalytic reactivity in Friedel–Crafts acylations of monobridged bis(cyclopentadienyl)molybdenum(I) carbonyl complexes

Doi:10.1016/j.poly.2018.03.021
(2018)

Article Doi