Tetrahedron Letters p. 5819 - 5822 (1992)
Update date:2022-07-30
Topics:
Tokitoh, Norihiro
Imakubo, Tatsuro
Okazaki, Renji
Sterically congested tris(arylchalcogeno)silyl chlorides were synthesized, and their reactions with silver perchlorate afforded unexpected products with a rearranged skeleton which were most likely formed via intermediary tris(arylchalcogeno)silicenium perchlorates.Key Words: silicenium ion; kinetic stabilization; rearrangement; tris(arylchalcogeno)silyl chloride; silver perchlorate
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Doi:10.1134/S1070428016090189
(2016)Doi:10.1248/cpb.40.1443
(1992)Doi:10.1002/anie.202000621
(2020)Doi:10.1039/c3nj00218g
(2013)Doi:10.1016/j.ejmech.2013.04.030
(2013)Doi:10.1039/c3cc44312d
(2013)
