Abnormal Reactions of Overcrowded Tris(arylchalcogeno)silyl Chlorides with Silver Perchlorate

DOI: 10.1016/0040-4039(92)89040-J

Source and publish data:

Tetrahedron Letters p. 5819 - 5822 (1992)

Update date:2022-07-30

Topics:

Authors:

Tokitoh, Norihiro

Imakubo, Tatsuro

Okazaki, Renji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(92)89040-J

Sterically congested tris(arylchalcogeno)silyl chlorides were synthesized, and their reactions with silver perchlorate afforded unexpected products with a rearranged skeleton which were most likely formed via intermediary tris(arylchalcogeno)silicenium perchlorates.Key Words: silicenium ion; kinetic stabilization; rearrangement; tris(arylchalcogeno)silyl chloride; silver perchlorate

Full text of DOI:10.1016/0040-4039(92)89040-J

Products guided by the article

Product name:1,3-Di-tert-butyl-5-tert-butylsulfanyl-benzene

Cas No:144775-51-9

R&D Labs maybe for 144775-51-9

NEWSTAR CHEM ENTERPRISE LTD.

Contact:0572-2722882

Address:1201,F3,xinghuibandao,
Yancheng Smiling Imp & Exp Co., Ltd.

Contact:+86-515-83173586

Address:Rm1207, BLD#03, Phoenix Plaza, Juheng Road, Yancheng, Jiangsu, P.R. China
Guangzhou Shiny Co., Ltd.

website:https://www.sinoshiny.com/products

Contact:+86-20-62802632;62802633

Address:Room 330 GIGCAS Building,No.511 Kehua Street,Tianhe District
Water Chemical Co.,LTD

Contact:+86-21-6856-1349 523-87676172

Address:No16 . BinJiang Road . Taixing Economy Developing Area .JiangSu Province . China
Zibo Fuxi'er Chemical Co.,Ltd （Shanxian Fuxi'er Chemical Co.,Ltd）

Contact:+86-533-2091422

Address:Eastern 4 on the 3th Road ,Liangxiang Industrial Park, Zibo city ,Shandong,China

Relevant to this article

Solvent-free synthesis of 4-oxoalkane-1,1,2,2-tetracarbonitriles

Doi:10.1134/S1070428016090189
(2016)
Novel phenoxyalkylamine derivatives. VII. Synthesis and pharmacological activities of 2-alkoxy-5-[(phenoxyalkylamino)alkyl]benzenesulfonamide derivatives

Doi:10.1248/cpb.40.1443
(1992)
A Direct Fluorescent Activity Assay for Glycosyltransferases Enables Convenient High-Throughput Screening: Application to O-GlcNAc Transferase

Doi:10.1002/anie.202000621
(2020)
Impact of the arrangement of functional moieties within small molecular systems for solution processable bulk heterojunction solar cells

Doi:10.1039/c3nj00218g
(2013)
Evaluation of Jatropha isabelli natural products and their synthetic analogs as potential antimalarial therapeutic agents

Doi:10.1016/j.ejmech.2013.04.030
(2013)
Accelerating influence of the gem-difluoromethylene group in a ring-closing olefin metathesis reaction. A Thorpe-Ingold effect?

Doi:10.1039/c3cc44312d
(2013)

Article Doi