Abnormal Reactions of Overcrowded Tris(arylchalcogeno)silyl Chlorides with Silver Perchlorate

DOI: 10.1016/0040-4039(92)89040-J

Source and publish data:

Tetrahedron Letters p. 5819 - 5822 (1992)

Update date:2022-07-30

Topics:

Authors:

Tokitoh, Norihiro

Imakubo, Tatsuro

Okazaki, Renji

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Article abstract of DOI:10.1016/0040-4039(92)89040-J

Sterically congested tris(arylchalcogeno)silyl chlorides were synthesized, and their reactions with silver perchlorate afforded unexpected products with a rearranged skeleton which were most likely formed via intermediary tris(arylchalcogeno)silicenium perchlorates.Key Words: silicenium ion; kinetic stabilization; rearrangement; tris(arylchalcogeno)silyl chloride; silver perchlorate

Full text of DOI:10.1016/0040-4039(92)89040-J

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