Tetrahedron Letters p. 5799 - 5802 (1992)
Update date:2022-08-02
Topics:
Matsuda
Sakakibara
Inoue
Nagashima
Propargylamines are effectively transformed to 2-dimethylphenylsilylmethyl-2-alkenals by the interaction of two equivalents of Me2PhSiH under silylformylation conditions catalyzed by Rh4(CO)12. The products are not obtained directly by silylformylation of the corresponding allenes.
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