Rhodium catalyzed transformation of propargylamines to 2-silylmethyl-2-alkenals: Formal silylformylation of allenes

DOI: 10.1016/0040-4039(92)89035-B

Source and publish data:

Tetrahedron Letters p. 5799 - 5802 (1992)

Update date:2022-08-02

Topics:

Authors:

Matsuda Matsuda

Sakakibara

Inoue Inoue

Nagashima

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Article abstract of DOI:10.1016/0040-4039(92)89035-B

Propargylamines are effectively transformed to 2-dimethylphenylsilylmethyl-2-alkenals by the interaction of two equivalents of Me₂PhSiH under silylformylation conditions catalyzed by Rh₄(CO)₁₂. The products are not obtained directly by silylformylation of the corresponding allenes.

Full text of DOI:10.1016/0040-4039(92)89035-B

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