Rhodium catalyzed transformation of propargylamines to 2-silylmethyl-2-alkenals: Formal silylformylation of allenes

DOI: 10.1016/0040-4039(92)89035-B

Source and publish data:

Tetrahedron Letters p. 5799 - 5802 (1992)

Update date:2022-08-02

Topics:

Authors:

Matsuda Matsuda

Sakakibara

Inoue Inoue

Nagashima

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(92)89035-B

Propargylamines are effectively transformed to 2-dimethylphenylsilylmethyl-2-alkenals by the interaction of two equivalents of Me₂PhSiH under silylformylation conditions catalyzed by Rh₄(CO)₁₂. The products are not obtained directly by silylformylation of the corresponding allenes.

Full text of DOI:10.1016/0040-4039(92)89035-B

Products guided by the article

Product name:(Z)-2-[(Benzyl-methyl-amino)-methyl]-3-(dimethyl-phenyl-silanyl)-propenal

Cas No:144776-83-0

R&D Labs maybe for 144776-83-0

Shanghai Sinofluoro Scientific Co., Ltd

Contact:+86-21-64279360

Address:Room 1006,Building 3,#58 East Xinjian Road, Shanghai ,201100,China,
Jiaxing Barton Chemicals

website:http://www.chinabarton.com

Contact:+86-573-82719618

Address:No. 162 Fumin Road, Honghe Town,
Hangzhou Mole's Science & Technology Co.,Ltd.(expird)

Contact:+86-571-56880228

Address:15F Guodu development Building, NO.182 Zhaohui Road
SHANDONG CREDAGRI CHEMICAL CO., LTD.

Contact:+86-531-88872050

Address:ROOM 601A, BUILDING 2, SHUNTAI SQUARE, NO. 2000 SHUNHUA ROAD, HI-TECH DEVELOPMENT ZONE, JINAN, CHINA.
Haitong Chemical Industrial Co.,Ltd.

website:https://www.haitonglongwin.com/

Contact:+86-022-66221018

Address:18-701, No.99, The 4th Street, TEDA,

Relevant to this article

Synthesis and characterization of a novel near-infrared fluorescent probe for living cells imaging

Doi:10.1166/jnn.2020.16942
(2020)
Tandem michael addition/cyclization reaction of 2,3-allenoates with organozincs: Facile synthesis of isocoumarins

Doi:10.1021/ol401625t
(2013)
Synthesis of an advanced precursor of demethoxyviridin

Doi:10.1080/00397911.2012.737078
(2013)
Synthesis, optical properties, and crystal structures of dithienostannoles

Doi:10.1021/om400213q
(2013)
Synthesis, characterization and biological screening of n-substituted (5-chloro-2-methoxyphenyl)benzene sulfonamide

Doi:10.14233/ajchem.2013.13735
(2013)
Substituent Effects in CH Hydrogen Bond Interactions: Linear Free Energy Relationships and Influence of Anions

Doi:10.1021/jacs.5b08767
(2015)

Article Doi