Samarium(II) Iodide promoted Reductive Fragmentation of γ-Halo Carbonyl Compounds: Application to the Enantiospecific Synthesis of (-)-Oudemansin A

DOI: 10.1039/c39920001218

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1218 - 1220 (1992)

Update date:2022-08-04

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Authors:

Honda, Toshio

Naito, Koichi

Yamane, Shin-ichi

Suzuki, Yukio

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Article abstract of DOI:10.1039/c39920001218

The reductive regioselective bond-cleavage reaction of γ-halo carbonyl compounds with samarium(II) iodide is developed and its utilisation in the enantiospecific synthesis of (-)-oudemansin A is described.

Full text of DOI:10.1039/c39920001218

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