Chiral Organosilicon Compounds in Asymmetric Synthesis of Chiral 1,3-Diols

DOI: 10.1021/jo00049a012

Source and publish data:

Journal of Organic Chemistry p. 6107 - 6111 (1992)

Update date:2022-07-30

Topics:

Authors:

Chan, T. H.

Nwe, K. T.

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Article abstract of DOI:10.1021/jo00049a012

Chiral 1,3-diols can be prepared in high enantiomeric purity (>99percent ee) from the reactions of the chiral silylcarbanion 2 with epoxides followed by oxidative cleavage of the carbon-silicon bond with hydrogen peroxide.The absolute configurations of so

Full text of DOI:10.1021/jo00049a012

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